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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '41e5c8e5b88111629e0fcec1ce5d021ff3ba82965a8ac537e853fce3b34af66e' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00017

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}