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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '90e0f12d12b531dc4cfbdb36cc4338d4485ebe4f2eb11d48205aa1e22f3c42a5' 
  AND token = 'Hr+JiJiRyxtNq6dcc1qUkGsfE7sOnKGdxrVfaTluTEA=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00024

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}