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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = 'a27a0320ea8503cfbcc6aa33338159cc9bc6dd9c3102f0bb1164f5876e6f2397' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00021

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}