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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = 'e9ad1893d5880767766fc520ea5ca75f34d3f9e1f3e2e24bc8c4029b566312d3' 
  AND token = 't7wsoHFiVGgHMIoxxEHtgoGt7nC6OTzUb9NmCiwqbq0=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00018

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}