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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = 'a7401df1721c5e5dbd09a8ead43184d90dc626688dbb15e6d6ed66228ddfa807' 
  AND token = 'b+Z4UaudEGoUMnj3MRUImjay3SwOpQl9i2iBLKm8km4=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00018

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}