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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = 'c099540b949444b7e56acef727828c78b3d8dccbf7a192200b40961c79a70a05' 
  AND token = 'QoG+AsRxWg9cgNKFWzyXMT29mS0GvMQXqDqgk0vDg2s=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00017

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}